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Lipase-Catalyzed Ring-Opening Polymerizations of 4-Substituted ε-Caprolactones: Mechanistic Considerations

✍ Scribed by Peeters, Joris W.; van Leeuwen, Oscar; Palmans, Anja R. A.; Meijer, E. W.

Book ID
125897478
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
199 KB
Volume
38
Category
Article
ISSN
0024-9297

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✍ Patrick Kerep; Helmut Ritter 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 97 KB

## Abstract **Summary:** The microwave (MW)‐assisted lipase‐catalyzed ring‐opening polymerization of __ε__‐caprolactone in boiling solvents was investigated for the first time. In case of boiling toluene or benzene the MW‐assisted reaction proceeded significantly slower compared to oil bath heating