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Ring-opening copolymerization of α-chloromethyl-α-methyl-β-propionolactone with ε-caprolactone

✍ Scribed by Xiang-Qian Liu; Zi-Chen Li; Fu-Sheng Du; Fu-Mian Li

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
61 KB
Volume
20
Category
Article
ISSN
1022-1336

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✦ Synopsis

a-Chloromethyl-a-methyl-b-propionolactone (CMMPL) has been copolymerized with e-caprolactone (CL) using a wide range of feed compositions and aluminium triisopropoxide [Al(O i Pr) 3 ] as an initiator. Random copolymers of CMMPL with CL were obtained. The pendant chloromethyl groups of the copolymer were converted to quaternary ammonium salts by reaction with pyridine, resulting in an increased hydrophilicity of the copolymers.

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