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Lipase-catalyzed enantioseparation of alcohols containing a tetrazole ring

✍ Scribed by Edyta Łukowska-Chojnacka; Urszula Bernaś; Jan Plenkiewicz

Book ID
113929634
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
689 KB
Volume
23
Category
Article
ISSN
0957-4166

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Lipase-catalyzed resolution of primary alcohol containing quaternary chiral carbon
✍ Chan Seong Cheong; Dai Sig Im; Jiyoung Kim; In O Kim 📂 Article 📅 1996 🏛 Springer Netherlands 🌐 English ⚖ 279 KB

2-Cyano-2-phenyl-I-hexanol containing chiral quatemary carbon was resolved using a lipase. Among various reaction conditions, transesterification reaction (solvent; n-hexane, lipase; Candida cylindracea) gave high selectivity(20/80). Additionally, the selectivity could be improved( 13187) when pyrid