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Line Intensity of R(0) and R(3) of the 12CH4 2ν3 Band from Diode Laser Spectroscopy

✍ Scribed by D Hurtmans; G Dufour; W Bell; A Henry; A Valentin; C Camy-Peyret

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
186 KB
Volume
215
Category
Article
ISSN
0022-2852

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✦ Synopsis

We have determined the spectroscopic parameters that are necessary to describe accurately the R(0) line profile of the CH 4 2ν 3 band from about 1 Torr to a few hundred Torr of pure CH 4 . The intensities determined at each pressure are in overall agreement to better than 0.7%. The R(3) manifold of the same band has also been investigated. Relative positions and absolute intensities of the three transitions composing the triplet have been determined. The intensity distribution inside the triplet is in fair agreement with recent theoretical predictions.

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