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Absolute Line Intensities in the ν3Band of12CH3F by Diode-Laser Spectroscopy

✍ Scribed by Muriel Lepère; Ghislain Blanquet; Jacques Walrand

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
189 KB
Volume
177
Category
Article
ISSN
0022-2852

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✦ Synopsis

Infrared absolute line intensities of the n 3 band of 12 CH 3 F have been measured around 9.5 mm using a diode-laser spectrometer. These line strengths were obtained from the equivalent width method and, for a few lines, by fitting a Rautian profile to the measured shape of the lines. From these results, we have deduced the vibrational bandstrength (S v 0 Å 379.2 { 5.9 cm 02 ratm 01 at 296 K) and the first Herman-Wallis factor (a Å 0.35 1 10 03 { 0.10 1 10 03 ).

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