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Limiting sedimentation and diffusion coefficients of polyelectrolytes. The charge effect

โœ Scribed by R. Varoqui; A. Schmitt

Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
842 KB
Volume
11
Category
Article
ISSN
0006-3525

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โœฆ Synopsis

General expressions relating the sedimentation and diffusion constants of polyelectrolytes to the friction properties of ionic components in multicomponent systems have been derived. A quantitative explanation of the charge effect with respect to the addition of a low-molecular-weight salt is given; special attention is laid on limiting laws according to the saltrto-polymer concentration ratio. The theory is applied to a simple model, the infinitely long rod-like model, to illustrate the peculiar aspect of the charge effect in presence of salt.

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