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Quantitative relationship between the surface charge density and dynamic charge of linear polyelectrolytes in the low charge-density limit

โœ Scribed by Kenneth S. Schmitz


Publisher
Wiley (John Wiley & Sons)
Year
1983
Tongue
English
Weight
206 KB
Volume
22
Category
Article
ISSN
0006-3525

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โœฆ Synopsis


The diffusive modes of polyions in moderate and low ionic-strength media are determined by a complex set of interactions which involve solvent, polyion, counterion, and co-ion particles. In an attempt to elucidate the relative effects of these interactions, Kowblansky and Zema' reported quasielastic light-scattering data on acrylamide/acrylic acid copolymers (viscosity-average molecular weight of 1.5

X 106 daltons) with different charge densities ([ = e2/ckTb, where e is the electron charge, E is the bulk dielectric constant, k T is the thermal energy, and b is the av-


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