From experimental data on impedance, IR, Raman and nuclear magnetic resonance spectroscopy it is shown that each lithium ion moves by "classical" hopping in Li3Sc2(PO4) 3 superionic crystals, i.e. the residence time rr is much greater than the time rf of flight. At the same time the charge transfer
✦ LIBER ✦
Li+/H+ion exchange in Li3 − 2xNbxM2 −x(PO4)3(M = In, Fe) materials with a NASICON structure
✍ Scribed by A. R. Shaikhlislamova; N. A. Zhuravlev; A. B. Yaroslavtsev
- Book ID
- 110182484
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2010
- Tongue
- English
- Weight
- 263 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0036-0236
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Fast-ion transport mechanism in Li3M2(PO
✍
Sergei E. Sigaryov
📂
Article
📅
1992
🏛
Elsevier Science
🌐
English
⚖ 255 KB
Some features of Li+-ion distribution in
✍
S.E. Sigaryov; E.A. Genkina; B.A. Maximov
📂
Article
📅
1990
🏛
Elsevier Science
🌐
English
⚖ 248 KB
Phase transitions and ion transport in N
✍
D. V. Safronov; I. A. Stenina; A. V. Maksimychev; S. L. Shestakov; A. B. Yarosla
📂
Article
📅
2009
🏛
SP MAIK Nauka/Interperiodica
🌐
English
⚖ 334 KB
Li mobility in Nasicon-type materials Li
✍
Arbi, K.; París, M. A.; Sanz, J.
📂
Article
📅
2011
🏛
Royal Society of Chemistry
🌐
English
⚖ 692 KB
Extensive lithium disorder in Li1.5Fe0.5
✍
Catti, Michele; Comotti, Angiolina; Di Blas, Silvia; Ibberson, Richard M.
📂
Article
📅
2004
🏛
Royal Society of Chemistry
🌐
English
⚖ 210 KB
Lithium mobility in titanium based Nasic
✍
K. Arbi; J.M. Rojo; J. Sanz
📂
Article
📅
2007
🏛
Elsevier Science
🌐
English
⚖ 229 KB
Titanium-based Nasicon-type compounds with formula Li 1+x Ti 2-x Al x (PO 4 ) 3 and LiTi 2-x Zr x (PO 4 ) 3 , have been prepared and studied with X-ray Diffraction (XRD), Nuclear Magnetic Resonance (NMR) and Electric Impedance (EI) techniques. From the analysis of the 7 Li and 31 P NMR spectra, cati