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Some features of Li+-ion distribution in monoclinic modifications of Li3M2(PO4)3 (M=Sc, Fe, In) superionic conductors

✍ Scribed by S.E. Sigaryov; E.A. Genkina; B.A. Maximov


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
248 KB
Volume
37
Category
Article
ISSN
0167-2738

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Fast-ion transport mechanism in Li3M2(PO
✍ Sergei E. Sigaryov πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 255 KB

From experimental data on impedance, IR, Raman and nuclear magnetic resonance spectroscopy it is shown that each lithium ion moves by "classical" hopping in Li3Sc2(PO4) 3 superionic crystals, i.e. the residence time rr is much greater than the time rf of flight. At the same time the charge transfer