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Light-Induced Excited-State Spin Trapping in Tetrazole-Based Spin Crossover Systems

✍ Scribed by Ordejón, Belén; de Graaf, Coen; Sousa, Carmen

Book ID
111644011
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
376 KB
Volume
130
Category
Article
ISSN
0002-7863

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Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1−xFex(ptz)6(BF4)2 spin-crossover systems
✍ A. Hauser 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 438 KB

Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t