Light-induced excited spin state trapping in a transition-metal complex: The hexa-1-propyltetrazole-iron (II) tetrafluoroborate spin-crossover system

Reversibility of light-induced excited s

Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1−xFex(ptz)6(BF4)2 spin-crossover systems

✍ A. Hauser 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 438 KB

Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t