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Light-induced excited-spin-state trapping (LIESST) in iron [Fe(2-Y-phen)3]X2 spin-crossover compounds

✍ Scribed by Poganiuch, P.; Guetlich, P.


Book ID
127053237
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
566 KB
Volume
26
Category
Article
ISSN
0020-1669

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## II IS known that [Fe(Z-mephen),] (C104)7 in the solid state IS an iron(H) spin-crossover system which shows light-induced excited spin state trapping (LIESST). The thermal spin-crossover behaviour of the complex [Fe(2-mephen)3]L+ embedded in various polymer matrices is similar to the solid-stat

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Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t