Light-induced excited-spin-state trapping (LIESST) in iron [Fe(2-Y-phen)3]X2 spin-crossover compounds
β Scribed by Poganiuch, P.; Guetlich, P.
- Book ID
- 127053237
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 566 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
## II IS known that [Fe(Z-mephen),] (C104)7 in the solid state IS an iron(H) spin-crossover system which shows light-induced excited spin state trapping (LIESST). The thermal spin-crossover behaviour of the complex [Fe(2-mephen)3]L+ embedded in various polymer matrices is similar to the solid-stat
Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t