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Light Induced Excited Pair Spin State in an Iron(II) Binuclear Spin-Crossover Compound

✍ Scribed by Létard, Jean-François; Real, José Antonio; Moliner, Nicolás; Gaspar, Ana B.; Capes, Laurence; Cador, Olivier; Kahn, Olivier

Book ID
126333177
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
71 KB
Volume
121
Category
Article
ISSN
0002-7863

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In iron(II) spin-crossover compounds, the transition from the 1 A 1 low-spin state at low temperatures to the 5 T 2 high-spin state at elevated temperatures is accompanied by a large increase in metal-ligand bond lengths. The resulting elastic interactions may be pictured as an internal pressure whi