Ligand Effects on ESR and Optical Properties of Gold Atoms in γ Irradiated Organic Solid Solutions at 77 K
✍ Scribed by Hase, Yoko Miyatake; Ito, Yoshitaka; Tajima, Yusuke
- Book ID
- 126223276
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 114 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0022-3654
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📜 SIMILAR VOLUMES
ESR spectra of CsO radical anions were detected for &/MCHX and C,,/MTHF solid solutions which were y-irradiated at 77 K and subsequently annealed at 1 IO-140 K. The g-factors were 2.00 19 and 1.9997 for C,,JMCHX (or CJMCHX-d14) and CJMTHF, respectively. AH,,=O.26 mT was obtained for those solutions
The nlion rJdinl of Icad(ll)Ictraphenylporphyrin W;IS produced by yndlolysisnnd by photolysis of the 1,1.2,2-tetrachloroethanc solutions at 77 K. The hfcc (0 0391 c~') dot to paired electron IS predommantly located m the porphyry ring. "'Pb observed in the CSR spectrum mduates lhat the un-1. introdu