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ESR spectra of C60 radical anions produced in γ-irradiated organic solid solutions at 77 K

✍ Scribed by Hirotomo Hase; Yoko Miyatake

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
380 KB
Volume
229
Category
Article
ISSN
0009-2614

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✦ Synopsis

ESR spectra of CsO radical anions were detected for &/MCHX and C,,/MTHF solid solutions which were y-irradiated at 77 K and subsequently annealed at 1 IO-140 K. The g-factors were 2.00 19 and 1.9997 for C,,JMCHX (or CJMCHX-d14) and CJMTHF, respectively. AH,,=O.26 mT was obtained for those solutions and was smaller than the values reported for electrolytically produced C, by about 50%. Matrix proton spin flip satellite lines were observed in CJMCHX.

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