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Lewis basicity of the [Co4O4]4+ cubane core. Preparation of a mixed-valence (4Co II , 4Co III ) cluster with an unusual [Co8(�4-O)4]2+ core, and new [Co4O3(OH)]5+ and [Co4O2(OH)2]6+ cubane complexes

✍ Scribed by Dimitrou, Katerina; Folting, Kirsten; Streib, William E.; Christou, George


Book ID
115508466
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
330 KB
Volume
0
Category
Article
ISSN
0022-4936

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OH), .4H,O was prepared by digesting Co,(OH),CO, .xH,O in water solution of NH,HCO,. Chemical analyses, diffuse reflectance spectroscopy and XRD data proved that this compound, like Na,Co,(CO,),(OH), . 6H,O and K,Co,(CO,),(OH), .4H,O, is a derivative of the kambaldaite Na