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Preparation and crystal structure of the ammonium cobalt carbonate hydroxide hydrate (NH4)2Co8(CO3)6(OH)6·4H2O

✍ Scribed by K. Petrov; E. Deleva; O. García-Martinez


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
471 KB
Volume
92
Category
Article
ISSN
0167-2738

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✦ Synopsis


OH), .4H,O was prepared by digesting Co,(OH),CO, .xH,O in water solution of NH,HCO,. Chemical analyses, diffuse reflectance spectroscopy and XRD data proved that this compound, like Na,Co,(CO,),(OH), . 6H,O and K,Co,(CO,),(OH), .4H,O, is a derivative of the kambaldaite Na


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Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c