Lewis Base Stabilized Phosphanylborane
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Karl-Christian Schwan; Alexey Y. Timoskin; Manfred Zabel; Manfred Scheer
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Article
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2006
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John Wiley and Sons
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English
⚖ 356 KB
## Abstract The abstraction of the Lewis acid from [W(CO)~5~(PH~2~BH~2~⋅NMe~3~)] (1) by an excess of P(OMe~3~)~3~ leads to the quantitative formation of the first Lewis base stabilized monomeric parent compound of phosphanylborane [H~2~PBH~2~⋅NMe~3~] 2. Density functional theory (DFT) calculations