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Lewis Acid/Base Stabilized Phosphanylalane and -gallane

✍ Scribed by Ulf Vogel; Alexey Y. Timoshkin; Manfred Scheer


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
105 KB
Volume
40
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


Lewis Base Stabilized Dichlorosilylene
✍ Rajendraβ€…S. Ghadwal; Herbertβ€…W. Roesky; Sebastian Merkel; Julian Henn; Dietmar S πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 359 KB
Lewis Base Stabilized Phosphanylborane
✍ Karl-Christian Schwan; Alexey Y. Timoskin; Manfred Zabel; Manfred Scheer πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 356 KB

## Abstract The abstraction of the Lewis acid from [W(CO)~5~(PH~2~BH~2~β‹…NMe~3~)] (1) by an excess of P(OMe~3~)~3~ leads to the quantitative formation of the first Lewis base stabilized monomeric parent compound of phosphanylborane [H~2~PBH~2~β‹…NMe~3~] 2. Density functional theory (DFT) calculations