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Controlled Oligomerization of Lewis Acid/Base-Stabilized Phosphanylalanes

✍ Scribed by Michael Bodensteiner; Ulf Vogel; Alexey Y. Timoshkin; Manfred Scheer

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 348 KB
Volume: 48
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200901064

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## Abstract Reactions of some typical acid halides of carbonic and trithiocarbonic acids and of orthophosphoric and sulfuric acids with Lewis acids and Lewis bases are compared. Acylium, perfluoroacylium, thioacylium, and even sulfonylium ions are obtainable with Lewis acids. It is possible by cond