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Lewis Acid-Catalyzed Synthesis of Aziridines

✍ Scribed by Brookhart, Maurice; Templeton, Joseph L.; Casarrubios, Luis; Pérez, Julio A.

Book ID: 111687522
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 113 KB
Volume: 61
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo961391w

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Lewis Acid Catalyzed Synthesis of Aziridines. -A convenient synthesis of the title compounds becomes possible in the presence of Lewis acids. The enamines (VI) and (VII), formed as by-products, can be easily removed by SiO2 chromatography. AlCl3 or TiCl4 generally give similar results.

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## Abstract Starting from alkyl‐substituted aziridines such as (VI) only moderate diastereoselectivity is achieved.

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