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ChemInform Abstract: Diastereoselective Synthesis of Oxazolidines and Imidazolidines via the Lewis Acid Catalyzed C—C Cleavage of Aziridines.

✍ Scribed by Zheng Jiang; Jing Wang; Ping Lu; Yanguang Wang


Book ID
112042851
Publisher
John Wiley and Sons
Year
2012
Weight
38 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Lewis Acid Catalyze
✍ L. CASARRUBIOS; J. A. PEREZ; M. BROOKHART; J. L. TEMPLETON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Lewis Acid Catalyzed Synthesis of Aziridines. -A convenient synthesis of the title compounds becomes possible in the presence of Lewis acids. The enamines (VI) and (VII), formed as by-products, can be easily removed by SiO2 chromatography. AlCl3 or TiCl4 generally give similar results.