Lewis Acid Catalyst Free Electrophilic Alkylation of Silicon-Capped π Donors in 1,1,1,3,3,3-Hexafluoro-2-propanol
✍ Scribed by Maxim O. Ratnikov; Vasily V. Tumanov; William A. Smit
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 292 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0044-8249
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Ring-opening of 1-CF 3 -substituted epoxy ethers with carboxylic acids was achieved in Et 3 N as solvent, and α-CF 3 -substituted acyloins and corresponding esters were obtained in good yields. In hexafluoro-2-propanol (HFIP) as solvent, the carboxylic acids acted as nucleophiles, and α-carbonyloxy