The first selenite chloride hydrates, Co(HSeO 3 )-Cl ´3 H 2 O and Cu(HSeO 3 )Cl ´2 H 2 O, have been prepared from solution and characterised by single-crystal X-ray diffraction. The cobalt phase adopts an unusual ªone-dimensionalº structure built up from vertex-sharing pyramidal [HSeO 3 ] 2± , and o
✦ LIBER ✦
‘Layered hydrogenselenite’ I. Synthesis, structure redetermination of [Cu(HSeO3)2(H2O)2] and determination of [Cu(HSeO3)2(NO3)2]2−·2NH4+,NH4NO3. Structural relationships of these complexes with [Cu(HSeO3)2]
✍ Scribed by A.M. Lafront; J.C. Trombe
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 525 KB
- Volume
- 234
- Category
- Article
- ISSN
- 0020-1693
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## The magnetic properties of Cu(NH-&(NO-& have been measured at low temperatures. Broad maxima in both the susceptibility and specific heat are observed and are consistent with linear chain behavior of a Heiscnberg antifcrromagnct, with J/k = -3.9 \* 0.1 K. Long-range order sets in at Tc = 0.15 +