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ChemInform Abstract: Syntheses and Structures of Two Selenite Chloride Hydrates: Co(HSeO3)Cl×3H2O and Cu(HSeO3)Cl×2H2O.

✍ Scribed by Magnus G. Johnston; William T. A. Harrison

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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Syntheses and Structures of Two Selenite
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The first selenite chloride hydrates, Co(HSeO 3 )-Cl ´3 H 2 O and Cu(HSeO 3 )Cl ´2 H 2 O, have been prepared from solution and characterised by single-crystal X-ray diffraction. The cobalt phase adopts an unusual ªone-dimensionalº structure built up from vertex-sharing pyramidal [HSeO 3 ] 2± , and o

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Synthesis and Structure of La(HSeO 3 )(SeO 4 )•2H 2 O. -Single crystals of the title compound representing a new mixed valence selenite/selenate are prepared in low yield within several months from an aqueous solution of La(NO 3 ) 3 , Co(NO 3 ) 2 , and SeO 2 . La(HSeO 3 )(SeO 4 )•2H 2 O (monoclinic,

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