Magnetic investigation of Cu(NH3)4(NO3)2
β Scribed by S.N. Bhatia; C.J. O'Connor; R.L. Carlin; H.A. Algra; L.J. de Jongh
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 357 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The magnetic properties of Cu(NH-&(NO-&
have been measured at low temperatures. Broad maxima in both the susceptibility and specific heat are observed and are consistent with linear chain behavior of a Heiscnberg antifcrromagnct, with J/k = -3.9 * 0.1 K. Long-range order sets in at Tc = 0.15 + 0.01 K, and the ratio kTdlJI = 0.038 is the lowest observed as yet for a one-dimensional, S = l/2 antifcrromagnct.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100Β±140 Β°C during 3Β±12 h. X-ray single crystal structures for isotypic I and II reveal the presence of