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Laser photolysis of 2-phenylheptamethyltrisilane

โœ Scribed by Peter P. Gaspar; Bong Hyun Boo; Sarangan Chari; Ashim K. Ghosh; Dewey Holten; Christine Kirmaier; Stanislaw Konieczny

Book ID
103027328
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
348 KB
Volume
105
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Two transient abwrptions have been detected III the 266 nm laser photol>sE of 2-phenylheptamethyltrisilane in cy~khexane solution at room temperature, and their time evolution was recorded in the presence and absence of air and added trapping agents The shorter-lived 440 nm transient (ttb 6 20 us) is tentatively a_w_ened to the silylene .SiMePh and the more persistent 380 nm transient to the dnilenc MePhSi=SiMePh The reactlvlty of thu silylene is much lower than had been expected

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