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Laser photolysis of 2-chloro-2-nitrosobutane. Kinetics and mechanism

✍ Scribed by Creagh, Linda T.; Trachenberg, Isaac


Book ID
126828830
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
496 KB
Volume
34
Category
Article
ISSN
0022-3263

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The reaction mechanism in the UV photochemistry of 2-chloro-2'-deoxyadenosine (Cladibrine) and 2-bromo-2'-deoxyadenosine in aqueous solution has been studied by laser photolysis at nanosecond time resolution. It is found that excitation at 266 nm wavelength produces heterolytic cleavage of the halog