Laser-induced fluorescence study of spin–orbit quenching of Cl(2P1/2) by H2, D2, and HD gases
✍ Scribed by Werschak, A.; Upadhyaya, H.P.; Volpp, H.-R.
- Book ID
- 122744261
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 242 KB
- Volume
- 551
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
In this work we studied the collinear F(\*P,$ + Hz system in a strong CO2 laser field. It was found that the tiajecror) surface hopping method (TSHM) yields entirely different results than the exact quantum-mechanical treatment. A curvecrossing model was devised to esplain the discrepancy.
Probabilities for the (VT) and (VR) deactivation of CO have been calculated from relaxation times measured down to 77 K using laser fluorescence. Only in the case of deactivation by p-H2 is the (VR) process important; its rate exceeds that for (VT) deactivation between 320 K and 110 K.