✦ LIBER ✦

Laser-induced fluorescence spectra of CH3O

✍ Scribed by Gen Inoue; Hajime Akimoto; Michio Okuda

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 342 KB
Volume: 63
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)87002-5

No coin nor oath required. For personal study only.

✦ Synopsis

Rcceib ed 8 .\lxch 1979 Tbc methow radical has been dire& detected b) ldser-induced fluorescence for the fusr tune. CwitJtion 't 7-92.6-3165 nm produces I%.torescence spec:m in tbe 300400 nm r~nze. The ewltcd state (A ' 1,) 1s at about 31600 cm-' aboLe the _rround stztt, and it has a ~lbrat!onJ mode at about 630 cm<, displays 2 progession at 1020 cm-t ~rhich corresponds to C-O stretchin;. The tfcorncence mterUs corresponding to C-O strachirtg in the gound state o('iX. Transitions are also obsertcd corresponding to one qantum of vrbmt~onal e\cttntlon ot tbs Cl-i3 deformation mode (1jSO cm-t) or of the bending mode of H3 -C-O (6SO cm-IL The fluorrsccnce lifetime of X "_~, is I .5 MS at 0 3 Torr.

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