𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Laser-induced fluorescence of matrix-isolated C4N+2

✍ Scribed by Jürgen Agreiter; Alice M. Smith; Martin Härtle; Vladimir E. Bondybey

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
853 KB
Volume
225
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

CIN$ (N=C-C=C-C=N+

) is produced in a self-igniting dc discharge from the neutral precursor seeded in neon and matrixisolated at 5.5 K. From Fourier-transform absorption, laser excitation and emission spectra of the cation's A *IIs * X *lIU transition the three symmetric C, vibrational modes were obtained for both states involved and are compared with the corresponding gas-phase values. Additional emission bands are assighed to combination and overtone bands involving the asymmetric stretches and two bending vibrations of the ground state. Subsidiary emission/absorption bands are interpreted as the forbidden ALL f 1 transitions which become allowed due to perturbations by the surrounding matrix.

📜 SIMILAR VOLUMES

Laser-induced fluorescence of matrix-iso
Laser-induced fluorescence of matrix-isolated HCCCCCN+ and HCCCCCCCN+
✍ Alice M. Smith; Jürgen Agreiter; Vladimir E. Bondybey 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 599 KB

The cyanodiacetylene (HCsN +) and cyanotriacetylene (HCTN +) cations were produced in a pulsed supersonic discharge through a dilute cyanoacetylene (HC3N) neon mixture, and isolated in solid neon at 5-7 K. The A 2 H-X 2II transitions of these cations were investigated by means of laser excitation an

Laser-induced fluorescence of CNN in an
Laser-induced fluorescence of CNN in an Ar matrix
✍ Brent E. Wurfel; Anton Thoma; Richard Schlachta; Vladimir E. Bondybey 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 386 KB

Fourier transform laser-induced fluorescence of CNN, A 'II+% 'Z-, in an argon matrix has been investigated. Eight new vibronic transitions have been found, indicating that the ground-state asymmetric stretch is 1419 cm-', about half the 2847 cm-' value of earlier studies. Reanalysis of the isotopic

Laser-induced fluorescence spectroscopy
Laser-induced fluorescence spectroscopy of an N+2-ion beam
✍ A. Ding; K. Richter; M. Menzinger 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 317 KB

Chem!str~ , i3rr11 ernr\_t of Toronto. Toronto. Omarro. Carlada M.5S I.41 Recelred 18 August 1980, in fiial form 10 h'ovembcr 1980 The mternal state dwrlbution of an N;-ion beam whuzh has been produced in a phsma eon source has been determmed b) Liser-Induced fluorescence The results show a marked d

IR-induced UV-visible fluorescence in ma
IR-induced UV-visible fluorescence in matrix-isolated CO
✍ J.P. Galaup; J.Y. Harbec; R. Charneau; H. Dubost 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 536 KB

UV-visible fluorescence from solid argon containing 1% or "C"O is observed upon irradiation hy n color-ccn~~ laser whose frequency is coincident with the lirst overtone absorption hand or CO. This emission consisls or an imsnse complex syswm bcwcen 650 and 800 nm and a weaker single progression rxlr