Laser induced fluorescence of a fast ion beam has been applied to 13 CO / 2 for its (0, 0, 0) A ˜2P u -(0, 0, 0) X ˜2P g UV electronic transition. The high resolution (0.005 cm 01 ) of the FIBLAS method, due to a highly reduced Doppler broadening, allows us to evaluate the isotopic shift, to appreci
Laser-induced fluorescence spectroscopy of an N+2-ion beam
✍ Scribed by A. Ding; K. Richter; M. Menzinger
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 317 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Chem!str~ , i3rr11 ernr_t of Toronto. Toronto. Omarro. Carlada M.5S I.41 Recelred 18 August 1980, in fiial form 10 h'ovembcr 1980 The mternal state dwrlbution of an N;-ion beam whuzh has been produced in a phsma eon source has been determmed b) Liser-Induced fluorescence The results show a marked devlatlon from a thermal Boltzmann dlsrrlbutlon Ion-beam den-SIU~S of less than 500 tons/cm 1x1 n pxtlcular wbratron-rotation state have been measured
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## CIN$ (N=C-C=C-C=N+ ) is produced in a self-igniting dc discharge from the neutral precursor seeded in neon and matrixisolated at 5.5 K. From Fourier-transform absorption, laser excitation and emission spectra of the cation's A \*IIs \* X \*lIU transition the three symmetric C, vibrational modes