๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Laser-induced fluorescence of C2H5S radicals

โœ Scribed by Graham Black; Leonard E. Jusinski

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
478 KB
Volume
136
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

C2HSS radicals were generated by 248 nm photodissociation of C2H5SH and CZHSSSCzHS and laser-induced fluorescence on the A-2 transition was studied. Prominent progressions are found in the C-S stretching mode which has a frequency of 408 zk 8 cm-' in the excited state and 681 f 15 cm-' in the ground state. The 08 band head lies at 440.0 nm. All the bands are highly predissociated with the lifetime decreasing from 75 ns for the 0: band to = 15 ns for the 38 band.

๐Ÿ“œ SIMILAR VOLUMES

Laser-induced fluorescence of i-C3H7S ra
Laser-induced fluorescence of i-C3H7S radicals
โœ Graham Black; Leonard E. Jusinski ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 498 KB

Iso-CpH,S radicals were generated by 248 nm photodissociation of i-&H,SH and laser-induced fluorescence of the A-2 transition was studied in the 395-435 nm region. A prominent series of bands in the excitation spectrum is interpreted as transitions to levels of the C-S stretching mode in the excited

Ultraviolet laser-induced fluorescence o
Ultraviolet laser-induced fluorescence of the C2H radical
โœ Yen-Chu Hsu; Pei-Ren Wang; Ming-Chieh Yang; D. Papousek; Yit-Tsong Chen; Whei-Yi ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 318 KB

In the spectral range 34500-40000 cm-1, two molecular species were detected by means of laser-induced fluorescence in the 193 nm photolysis of acetylene: one is C2(a 3Hu), the other is most likely C2H(X). The identification of C2H is based upon the rotational constants (B"= 1.4397-1.4534 cm-t), the

Laser-induced fluorescence of the SiCl2
Laser-induced fluorescence of the SiCl2 radical
โœ Makoto Suzuki; Nobuaki Washida; Gen Inoue ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 614 KB

Dichlorosilylene, Sic12 , in the gas phase has been detected by laser-induced fluorescence of the x 'B1-?? 'Al transition in the 309-333 mn region. The wavenumber of the 0: transition is determined to be 30003.6 f 0.5 cm-' (333.20 nm). The fundamental vibrational frequencies are assigned to be IJ~ =

The reaction of C2F5 radicals with H2S
The reaction of C2F5 radicals with H2S
โœ J. E. Bassett; E. Whittle ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 410 KB

The reaction of CzF5 radicals with HzS (2) C2F5 + HzS -+ CzF5H + HS kfi was studied over the range 1"-123"C using CZFS radicals generated by photolysis of perfluoropropionic anhydride. The rate constant k~ for reaction (2) is given by where e = 2.303RT/cal mole-'. The relevance of this result to c