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Laser-excited fluorescence detection of SiH2 produced in IR MPD of organosilanes

✍ Scribed by J.W. Thoman Jr.; J.I. Steinfeld

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
357 KB
Volume
124
Category
Article
ISSN
0009-2614

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✦ Synopsis

SiH, has been identified as a photolysis product in the infrared multiple-photon dissociation of RSiH, (R = n-butyl, phenyl), arising from secondary IR MPD of the silane produced in the initial four-center elimination step. The radiative lifetimes of A'B, levels show a strong rotational-state dependence.

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