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Large inclusion constants ofβ-cyclodextrin with carborane derivatives

✍ Scribed by Rimantas Vaitkus; Stefan Sjöberg

Publisher
Springer Netherlands
Year
2010
Tongue
English
Weight
240 KB
Volume
69
Category
Article
ISSN
0923-0750

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Complexation of β-cyclodextrin with carb
Complexation of β-cyclodextrin with carborane derivatives in aqueous solution
✍ Kiminori Ohta; Shunsuke Konno; Yasuyuki Endo 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 269 KB

b-Cyclodextrin formed the most robust complexes with o-carboranols 1b and 1c in aqueous solution, and the association constants estimated from NMR titration studies indicated K a >1 Â 10 6 M À1 and K a = 6 Â 10 5 M À1 , respectively.

Inclusion complex of fenbufen with β-cyc
Inclusion complex of fenbufen with β-cyclodextrin
✍ I. Bratu; J. M. Gavira-Vallejo; A. Hernanz; M. Bogdan; Gh. Bora 📂 Article 📅 2004 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 108 KB 👁 1 views

## Abstract An inclusion complex of fenbufen with β‐cyclodextrin (β‐CD) in aqueous solution was characterized by ^1^H‐NMR spectroscopy. The [1:1] stoichiometry was determined and a stability constant of several 1000s (__M__^−1^) was calculated. The geometry of the inclusion complex was established