Lampteromyces bioluminescence: 3. Structure of lampteroflavin, the light emitter in the luminous mushroom, L. japonicus
β Scribed by Duangchan Uyakul; Minoru Isobe; Toshio Goto
- Book ID
- 107873812
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 341 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0045-2068
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## The synthesis of lamprerojlavin (the hght emitter of the lumrnous mushroom, Lampteromyces japonicus) is described. Protected riboflavin was stereoselecrively glycosylared wirh ribofuranosyl imidate to give largely rhe a-product Chloroethyl group which could be removed under neutral condition conr
## Lampteroflavin (1, Lf) was isolated from the suspension of alive gills of the luminous mushroom, Lampteromycea japonicus. It was hydrolyzed into riboflavin (2, Rf) and D-riboee, which were identified by means of HE&C, NMR, CD and FAB-MS/MS. The structure was concluded to be 5'-riboflavinyl a-