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Chemical synthesis of lampteroflavin as light emitter in the luminous mushroom, lampteromyces japonicus

✍ Scribed by Hiroyuki Takahashi; Minoru Isobe; Toshio Goto

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 596 KB
Volume: 47
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86553-4

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✦ Synopsis

The synthesis of lamprerojlavin (the hght emitter of the lumrnous mushroom, Lampteromyces japonicus) is described. Protected riboflavin was stereoselecrively glycosylared wirh ribofuranosyl imidate to give largely rhe a-product Chloroethyl group which could be removed under neutral condition conrrrbured to this synthesis.

Lampteroflavin (Lf) 1 was isolated from the luminous mushroom, Lampteromyces japomcus, in 1987 by Isobe et al 1) as its bioluminescence light emitter. We are interested in the unique structure of 1 among

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