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Lampteroflavin, the first riboflavinyl alpha ribofuranoside as light emitter in the luminous mushroom, l. japonicus

✍ Scribed by Duangchan Uyakul; Minoru Isobe; Toshio Goto

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 869 KB
Volume: 46
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86700-4

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✦ Synopsis

Lampteroflavin

(1, Lf)

was isolated from the suspension of alive gills of the luminous mushroom, Lampteromycea japonicus.

It was hydrolyzed into riboflavin (2, Rf) and D-riboee, which were identified by means of HE&C, NMR, CD and FAB-MS/MS. The structure was concluded to be 5'-riboflavinyl a-D-ribofuranoside.

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## The synthesis of lamprerojlavin (the hght emitter of the lumrnous mushroom, Lampteromyces japonicus) is described. Protected riboflavin was stereoselecrively glycosylared wirh ribofuranosyl imidate to give largely rhe a-product Chloroethyl group which could be removed under neutral condition conr