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La3Ni2O6: A New Double T′-Type Nickelate with Infinite Ni1+/2+O2 Layers.

✍ Scribed by Viktor V. Poltavets; Konstantin A. Lokshin; Sibel Dikmen; Mark Croft; Takeshi Egami; Martha Greenblatt


Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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A novel molybdenum(V) phosphate decorated with nickel complex cations, Ni[Mo 6 O 12 (OH) bipy=2,2'-bipyridyl), has been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction. Two {Mo 6 P 4 } clusters are linked via one Ni cation to form a Ni[Mo 6 P 4 ] 2 dimer