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A Mixed Cation Nickel Diphosphate with a Layered Intergrowth Structure: Synthesis, Structural and Magnetic Characterization of Na(NH4) [Ni3(P2O7)2 (H2O)2].

✍ Scribed by Wei Liu; Xin Xin Yang; Hao Hong Chen; Ya Xi Huang; Walter Schnelle; Jing Tai Zhao


Publisher
John Wiley and Sons
Year
2005
Weight
11 KB
Volume
36
Category
Article
ISSN
0931-7597

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Single crystals of (4-ClC 7 H 6 NH 3 ) 9 [Nd(P 6 O 18 ) 2 ].9H 2 O were synthesized in aqueous solution. This compound crystallizes in a triclinic P1 unit-cell, with a = 14.898( 6), b = 18.049( 7), c = 20.695(6)Γ…, Ξ± = 102.04(3), Ξ² = 100.49(3), Ξ³ = 98.82(3)Β°, V = 5245(4) 3 Γ… and Z = 2. The crystal s