✦ LIBER ✦

A Novel One-dimensional Reduced Molybdenum(V) Decorated with Nickel Coordination Cations:Ni[Mo6O12(OH)3(PO4)(HPO4)3]2[Ni(H2O)2][Ni(H2O)(bipy)2]4·5H2O

✍ Scribed by Hong-Xu GUO; Qing-Hua WANG; Chen CHEN; Min LIANG; Ling CHEN

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 189 KB
Volume: 26
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.200890121

No coin nor oath required. For personal study only.

✦ Synopsis

A novel molybdenum(V) phosphate decorated with nickel complex cations, Ni[Mo 6 O 12 (OH)

bipy＝2,2'-bipyridyl), has been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction. Two {Mo 6 P 4 } clusters are linked via one Ni cation to form a Ni[Mo 6 P 4 ] 2 dimer unit, which is further connected together by additional nickel coordination complex ions to give 1-D molybdenum(V) phosphate chain-like structure. A probe reaction of the oxidation of benzaldehyde with H 2 O 2 using the title compound as catalyst was carried out in a liquid-solid system, showing that the compound had high oxidative catalytic activity to the reaction.

📜 SIMILAR VOLUMES

Open-Framework Nickel Succinate, [Ni7(C4

Open-Framework Nickel Succinate, [Ni7(C4H4O4)6(OH)2(H2O)2]⋅2 H2O: A New Hybrid Material with Three-Dimensional Ni−O−Ni Connectivity

✍ Paul M. Forster; Anthony K. Cheetham 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 148 KB 👁 1 views

Open-Framework Nickel Succinate, [Ni7(C4

Open-Framework Nickel Succinate, [Ni7(C4H4O4)6(OH)2(H2O)2]⋅2 H2O: A New Hybrid Material with Three-Dimensional Ni−O−Ni Connectivity

✍ Paul M. Forster; Anthony K. Cheetham 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 148 KB 👁 1 views

A Nickel Molybdenum Phosphate with Tunne

A Nickel Molybdenum Phosphate with Tunnel: Hydrothermal Synthesis and Structure of (NH3CH2CH2NH3)4 · (NH3CH2CH2NH2) · Na · [Ni2Mo12O30(PO4)(HPO4)4(H2PO4)3] · 6H2O

✍ Lin Xu; Yaqiu Sun; Enbo Wang; Enhong Shen; Zhongri Liu; Changwen Hu; Yan Xing; Y 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 158 KB

A nickel molybdenum phosphate, (NH 3 CH 2 CH 2 NH 3 ) 4 ' (NH 3 CH 2 CH 2 NH 2 ) ' Na ' [Ni 2 Mo 12 O 30 (PO 4 ) (HPO 4 ) 4 (H 2 PO 4 ) 3 ] ' 6H 2 O, involving molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray di4raction. De

[Ni(H2O)6]2 [Na(H2O)3]2 [V10O28]×4H2O, B

[Ni(H2O)6]2 [Na(H2O)3]2 [V10O28]×4H2O, Bis(nickel hexahydrate) Bis(sodium trihydrate) Decavanadate Tetrahydrate.

✍ Tomoyuki Higami; Masato Hashimoto; Seichi Okeya 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 57 KB 👁 1 views

ChemInform Abstract: A Hydrothermal Inve

ChemInform Abstract: A Hydrothermal Investigation of the 1/2V2O5—H2C2O4 /H3PO4/NH4OH System: Synthesis and Structures of (NH4)VOPO4×1.5H2O, (NH4)0.5VOPO4×1.5H2O, (NH4)2[VO(H2O)3]2 [VO(H2O)] [VO(PO4)2]2×3H2O, and (NH4)2 [VO(HPO4)] 2(C2O4)×5H2O.

✍ Junghwan Do; Ranko P. Bontchev; Allan J. Jacobson 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 40 KB 👁 1 views

Synthesis, Crystal Structure and Thermal

Synthesis, Crystal Structure and Thermal Behavior of Co(en)3[B4O5(OH)4]Cl·3H2O and [Ni(en)3][B5O6(OH)4]2·2H2O

✍ Lijuan ZHENG; Jianjian ZHANG; Zhihong LIU 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views