Kinetics of the Reactions of N( 4 S) Atoms with O 2 and CO 2 over Wide Temperatures Ranges
β Scribed by Fernandez, Abel; Goumri, A.; Fontijn, Arthur
- Book ID
- 126444830
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 118 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The kinetics of the reaction of 0 atoms with NO2 was investigated in the temperature range 199-357 K. The value of the rate constant can be expressed by k, = (5.21 kO.50) x lo-'\* exp [(202\*27)lT] cm3 s-' (3~ error). At temperatures below 230 K, the formation of equilibrium concentrations of N204 a
The rate constants for the reaction of CN with NzO and COz have been measured by the laser dissociation/laser-induced fluorescence (two-laser pump-probe) technique at temperatures between 300 and 740 K. The rate of CN + NzO was measurable above 500 K, with a least-squares averaged rate constant, k =