Kinetics of Pb Reactions with N 2 O, Cl 2 , HCl, and O 2 at High Temperatures
β Scribed by Cosic, Biljana; Fontijn, Arthur
- Book ID
- 127350975
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 77 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The rate constant for the reaction (I), C1+ HOz -HCI + 0 2 , was measured using molecular modulation spectrometry to investigate HOz radical kinetics in the modulated photolysis of ClyH2-02 mixtures at 760 torr pressure. HOz was monitored directly in absorption at 220 nm, and k l was determined from
The kinetics of the reaction of 0 atoms with NO2 was investigated in the temperature range 199-357 K. The value of the rate constant can be expressed by k, = (5.21 kO.50) x lo-'\* exp [(202\*27)lT] cm3 s-' (3~ error). At temperatures below 230 K, the formation of equilibrium concentrations of N204 a
The reaction of O-atoms with cyanogen was studied behind reflected shock waves using mixtures of nitrous oxide and cyanogen dilute in argon (10/100, 15/150, and 30/300 ppm N20/ppm C2N2, with temperatures in the range 1780 \_< T ~ 2285K and pressures of about 1.9 bar. Generation of O-atoms was achiev