Kinetics of the reaction of methyl radicals with nitrogen dioxide
β Scribed by Fumiaki Yamada; Irene R. Slagle; D. Gutman
- Book ID
- 107732885
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 283 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio
The kinetics of CFs radicals with NO2 have been investigated. CFs radicals were generated by infrared multiphoton dissociation of CFJ in the presence of NO\*. The absolute reaction rate constant was measured at 300 4 4 K as (2.5 C 0.4) x 10-l' cm3 molecule-' s-' from monitoring the rise time of C&O
The reaction of NO2 with CzF4 was studied at 30Β°, 68", 114O, and 157Β°C by in situ monitoring the infrared absorption bands of the products. The major primary products of the reaction are OzNCFzCFO and FNO. Smaller amounts of CFZO (and presumably NO) are also produced. There was no evidence for other