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Temperature and pressure dependent kinetics of the gas-phase reaction of the hydroxyl radical with nitrogen dioxide

✍ Scribed by Dransfield, Timothy J.; Perkins, Katherine K.; Donahue, Neil M.; Anderson, James G.; Sprengnether, Michele M.; Demerjian, Kenneth L.


Book ID
119653133
Publisher
American Geophysical Union
Year
1999
Tongue
English
Weight
532 KB
Volume
26
Category
Article
ISSN
1944-8007

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The kinetics of the reaction CHs + OH ( +M ) -CH,OH( + M ) was studied in the temperature range 283-373 K and in the pressure range 85-1000 mbar SF, by pulse radiolysis combined with UV absorption spectroscopy. The methyl and hydroxyl radical decays were followed by monitoring the transient UV absor

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The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M