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Rate measurement of reactions of trifluoromethyl radicals with nitrogen dioxide

✍ Scribed by Joseph S. Francisco; Zhuangjie Li

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
495 KB
Volume
162
Category
Article
ISSN
0009-2614

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✦ Synopsis

The kinetics of CFs radicals with NO2 have been investigated. CFs radicals were generated by infrared multiphoton dissociation of CFJ in the presence of NO*. The absolute reaction rate constant was measured at 300 4 4 K as (2.5 C 0.4) x 10-l' cm3 molecule-' s-' from monitoring the rise time of C&O time-resolved vibrational fluorescence.

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