Kinetics of the reaction of HO2 with CH3C(O)O2 in the temperature range 253–368 K
✍ Scribed by Geert K. Moortgat; Bernard Veyret; Robert Lesclaux
- Book ID
- 107734627
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 374 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0009-2614
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## Abstract A direct kinetics study of the temperature dependence of the CH~2~O branching channel for the CH~3~O~2~ + HO~2~ reaction has been performed using the turbulent flow technique with high‐pressure chemical ionization mass spectrometry for the detection of reactants and products. The temper
The rate constant of the reaction OH (v = 0) + O3 5 HOa + 02 was measured over the temperature range from 220 to 4-50'K at total pressures between 2 and 5 torr using ultraviolet fluorescent scattering for the detection of OH radicals. An Arrhenius spression, ICI = 1.3 X lo-l2 x esp(-1900/RT) cm3/s
## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0