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Kinetics of the reaction of cyclopentane with trichloroethylene

✍ Scribed by T. J. Hardwick

Publisher: John Wiley and Sons
Year: 1969
Tongue: English
Weight: 503 KB
Volume: 1
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550010305

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✦ Synopsis

The. kinetics of the thermally and radiation initiated chain reaction between trichloroethylene and cyclopentane to produce 1,l -dichlorovinylcyclopentane and hydrogen chloride have been investigated in the temperature range 250-360°C at high pressure in the gas phase. The rate governing step in the chain is C,H, + C,HCl, a C,H,CH = CCl, + C1 (k3 = 3.3 x loy exp -( 4 8 0 0 / R T ) cc molep1 sec-l). The rate of the unimolecular decomposition of trichloroethylene is 1.4 x 1014 exp -(61,20O/RT) seccl.

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