## Reactions m hqurd dlcyclopentadiene were mduced by CO2 laser pulses. Heterogeneous sensltlzation was achieved by means of suspended graphite or a breakdown plasma at the surface The dlstriiutlon of products can be explamed in terms of tigh temperatures occurnng in the reaction rolume for a very
CO2 laser induced reactions of trichloroethylene
β Scribed by Kwang Yul Choo; Tai Jong Kang; Q.Won Choi
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 237 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The pressure and laser-power dependence of the product distributions in the TEA CO2 laser induced decomposition of trichloroethylene were studied. At moderate pressures molecular elimination of HCI to give CCkCCI vi.r intcrmolecuIar enemy transfer was found to be the major reaction path. At low pressures a pure laser-induced C-Cl bond fiiion to pive CH=CCI was found to be the primary reaction step_
π SIMILAR VOLUMES
## Abstract The multiple photon absorption and decomposition of ethanol irradiated by pulsed 9P18 infrared radiation (1048.7 cm^β1^) from a TEA CO~2~ laser has been studied in the fluence range 15 to 5 J cm^β2^. The absorption crossβsection is pressureβdependent due to rapid collisional rotational
in CO,(u, mode) is studied extensively in CO,, CO: + ' 4 N, , CO, t ' 'N, and CO,+ Hc by USC of the laser induced fluorescence technique coverin, e the entire range of concentration (O-100 per cent) in the temperature range ZOO-500Β°K. While the data on composition yield better average values for the
The nascent rotational and fine-structure state distributions in OH (o = 0) produced in the endothermic reaction H + CO2 OH + CO have been measured with hot hydrogen atoms from the photodissociation of HBr at 193 nm. Considerable OH rotational excitation broadly peaked at around K = 11 is observed.