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Kinetics of the reaction of atomic hydrogen with methyl hydroperoxide

✍ Scribed by F. Šslemr; P. Warneck

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
854 KB
Volume
9
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The reaction H + CH~3~OOH was investigated under conditions of excess atomic hydrogen concentration using a flow reactor attached to a photoionization mass spectrometer. The rate coefficient of the reaction was determined as

The three important reaction channels were found to be
equation image
with the individual contributions determined as indicated. The product methoxy and methylperoxy radicals react mainly with atomic hydrogen under the employed experimental conditions according to
equation image
where the estimates for the percentage contributions of the various channels were derived from the measured product yields.

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